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SOLVED:In 1922 Donald D. van Slyke ( J. Biol. Chem., 52, 525) defined a quantity known as the buffer index: β=d cb / d(pH), where d cb represents the increment of moles of strong base to one liter of the buffer. For the addition of a strong acid, he wrote β=-d ca / d(pH) By applying this idea to a monoprotic acid and its conjugate base, we can derive the following expression: β=2.303((Kw)/([H3 O^ ]) [H3 O^ ] (c Ka[H3 O^ ])/((Ka [H3 O^ ])^2)) where c is the total concentration of monoprotic acid
SOLVED:In 1922 Donald D. van Slyke ( J. Biol. Chem., 52, 525) defi…
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